Iron speciation in atmospherically processed aerosols

نویسندگان

  • B. J. Majestic
  • M. M. Shafer
چکیده

Application of synchrotron radiation for measurement of iron red-ox speciation in atmospherically processed aerosols B. J. Majestic, J. J. Schauer, and M. M. Shafer Environmental Chemistry and Technology Program, University of Wisconsin – Madison, 660 N. Park St, Madison, WI 53706, USA Received: 10 January 2007 – Accepted: 17 January 2007 – Published: 29 January 2007 Correspondence to: J. J. Schauer ([email protected])

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Application of Synchrotron Radiation for Measurement of Iron Red-ox Speciation in Atmospherically Processed Aerosols

In this study, ambient atmospheric particulate matter samples were collected using a size-resolved impactor sampler from three urban sites. The purpose of this study is to gain a better understanding of transformations of aerosolbound iron as it is processed in the atmosphere. Thus, the aerosol samples were artificially aged to represent long-term transport (10 to 40 days) or short-term transpo...

متن کامل

Iron profiles and speciation of the upper water column at the Bermuda Atlantic Time-series Study site: a model based sensitivity study

A one-dimensional model of the biogeochemistry and speciation of iron is coupled with the General Ocean Turbulence Model (GOTM) and a NPZD-type ecosystem model. The model is able to simulate the temporal patterns and vertical profiles of dissolved iron (dFe) in the upper ocean at the Bermuda Atlantic Time-series Study site reasonably well. Subsurface model profiles strongly depend on the parame...

متن کامل

Characterization of iron speciation in urban and rural single particles using XANES spectroscopy and micro X-ray fluorescence measurements: investigating the relationship between speciation and fractional iron solubility

Soluble iron in fine atmospheric particles has been identified as a public health concern by participating in reactions that generate reactive oxygen species (ROS). The mineralogy and oxidation state (speciation) of iron have been shown to influence fractional iron solubility (soluble iron/total iron). In this study, iron speciation was determined in single particles at urban and rural sites in...

متن کامل

Selective Speciation of Ferric Iron by a New Heterocyclic Ligand

The synthesis and analytical applications of the new heterocyclic ligand are described. The complexation reaction of the ligand with some cations was studied in aqueous methanol at room temperature using the spectrophotometric method. Results revealed that only the absorption spectra of the Fe (III)–ligand complex show a high redshift of the absorption maximum in the aqueous methanol soluti...

متن کامل

Impacts of atmospheric nutrient deposition on marine productivity: Roles of nitrogen, phosphorus, and iron

[1] Nutrients are supplied to the mixed layer of the open ocean by either atmospheric deposition or mixing from deeper waters, and these nutrients drive nitrogen and carbon fixation. To evaluate the importance of atmospheric deposition, we estimate marine nitrogen and carbon fixation from present‐day simulations of atmospheric deposition of nitrogen, phosphorus, and iron. These are compared wit...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2007